Simulation of mercury capture by activated carbon injection in incinerator flue gas. 1. In-duct removal.

A detailed model for the in-duct mercury capture in incinerator flue gas by powdered activated carbon injection is presented. Material balances on mercury in both gaseous and adsorbed phases are carried out along the duct length and inside the activated carbon particles, taking into account mass transfer resistances and adsorption kinetics. The set of the coupled partial differential equations is transformed by means of an orthogonal collocation technique and integrated using a Runge-Kutta method with adaptive stepsize control. The model has been applied to several sorbents of practical interest, whose parameters have been evaluated from available literature data. The values and range of the operating variables have been chosen in order to simulate typical incinerators operating conditions. Results of simulations indicate that large sorbent loadings in the duct are needed to obtain high mercury removal efficiencies, due to the short residence times. As a consequence very low utilization of the sorbents is achieved in any case. To minimize the sorbent feed rate it is particularly advisable to use a reactive sorbent and to lower the operating temperature as much as possible. Improvements in the mercury capture performance can be obtained also by increasing the in-duct particles residence time and by decreasing the sorbent particles size. Model results are compared with available relevant full scale data.