| Literature DB >> 11706251 |
A R Kennedy1, R E Mulvey, J H Schulte.
Abstract
The metallation reaction between dibutylmagnesium and 2,6-diisopropyl-N-(trimethylsilyl)aniline gives the unusual monomeric three-coordinate complex (diethyl ether-kappa O)bis[2,6-diisopropyl-N-(trimethylsilyl)anilido-kappa N]magnesium(II), [Mg(C(15)H(26)NSi)(2)(C(4)H(10)O)] or [Mg[(Me(3)Si)(2,6-(i)Pr(2)C(6)H(3))N](2)(Et(2)O)]. This low-coordinate species has a distorted trigonal-planar coordination environment, with an additional short Mg-C(ipso) contact of 2.799 (2) A.Entities:
Year: 2001 PMID： 11706251 DOI： 10.1107/s0108270101014408
Source DB: PubMed Journal: Acta Crystallogr C ISSN： 0108-2701 Impact factor: 1.172