Literature DB >> 11700139

An exceptional hydroboration of substituted fluoroolefins providing tertiary alcohols.

P V Ramachandran1, M P Jennings.   

Abstract

[reaction--see text] A rare hydroboration-oxidation providing tertiary-alcohols has been achieved in the case of 1,1,2-perfluoroalkyl(aryl)ethylenes. The hydroboration of substituted perfluoroalkyl(aryl)ethylenes with dichloroborane reveals that the regioselectivity does not entirely depend on the electronics of the fluoroolefins.

Entities:  

Year:  2001        PMID: 11700139     DOI: 10.1021/ol016779e

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Synthesis and applications of α-trifluoromethylated alkylboron compounds.

Authors:  O Andreea Argintaru; DaWeon Ryu; Ioana Aron; Gary A Molander
Journal:  Angew Chem Int Ed Engl       Date:  2013-11-07       Impact factor: 15.336

Review 2.  Recent Advances in the Construction of Fluorinated Organoboron Compounds.

Authors:  Xingxing Ma; Zhijie Kuang; Qiuling Song
Journal:  JACS Au       Date:  2021-12-30
  2 in total

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