Capillary instabilities in thin nematic liquid crystalline fibers.

A complete identification and characterization of three distinct capillary instabilities in nematic liquid crystal fibers is presented. Linear stability analysis of capillary instabilities in thin nematic liquid crystalline cylindrical fibers is performed by formulating and solving the governing nematocapillary equations. A representative axial nematic orientation texture is studied. The surface disturbance is expressed in normal modes, which include the azimuthal wavenumber m to take into account nonaxisymmetric modes of the disturbance. Capillary instabilities in nematic fibers reflect the anisotropic nature of liquid crystals, such as the orientation contribution to the surface elasticity and surface bending stresses. Surface gradients of bending stresses provide additional anisotropic contributions to the capillary pressure that may renormalize the classical displacement and curvature forces that exist in any fluid fiber. The exact nature (stabilizing and destabilizing) and magnitude of the renormalization of the displacement and curvature forces depend on the nematic orientation and the anisotropic contribution to the surface energy, and accordingly capillary instabilities may be axisymmetric or nonaxisymmetric, with finite or unbounded wavelengths. Thus, the classical fiber-to-droplet transformation is one of several possible instability pathways while others include surface fibrillation.