| Literature DB >> 11678700 |
G R Cook1, S Sankaranarayanan.
Abstract
[reaction: see text]. The allylic substitution of racemic 5-vinyloxazolidinones with phthalimide and a chiral palladium catalyst afforded optically enriched regioisomeric products. Optimal divergence was found by employing chiral DIOP ligands in toluene. These results demonstrate the influence of chiral ligand/chiral substrate matching on the regioselectivity in a novel resolution strategy.Entities:
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Year: 2001 PMID： 11678700 DOI： 10.1021/ol016633f
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005