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Literature DB >> 11674094

Electrolytic Partial Fluorination of Organic Compounds. 30.(1) Drastic Improvement of Anodic Monofluorination of 2-Substituted 1,3-Oxathiolan-5-ones Using the Novel Fluorine Source Et(4)NF.4HF.

Seiichiro Higashiya¹, Satoru Narizuka, Akinori Konno, Tomoko Maeda, Kunitaka Momota, Toshio Fuchigami.

Abstract

The highly regioselective anodic monofluorination of 2-substituted 1,3-oxathiolan-5-ones was successfully carried out using a novel supporting electrolyte, Et(4)NF.4HF, while use of a conventional supporting electrolyte, Et(3)N.3HF, resulted in no formation or extremely low yields of the fluorinated products.

Entities: Chemical

Year: 1999 PMID： 11674094 DOI： 10.1021/jo981437g

Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354

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Cited

1 in total

1. An automated synthesizer for electrochemical ¹⁸F-fluorination of organic compounds.

Authors: Christopher M Waldmann; Artem Lebedev; Nathaniel Allison; Saman Sadeghi
Journal: Appl Radiat Isot Date: 2017-06-21 Impact factor: 1.513

1 in total

Electrolytic Partial Fluorination of Organic Compounds. 30.(1) Drastic Improvement of Anodic Monofluorination of 2-Substituted 1,3-Oxathiolan-5-ones Using the Novel Fluorine Source Et(4)NF.4HF.

1. An automated synthesizer for electrochemical 18F-fluorination of organic compounds.

1. An automated synthesizer for electrochemical ¹⁸F-fluorination of organic compounds.