| Literature DB >> 11671989 |
Ivo Leito1, Toomas Rodima, Ilmar A. Koppel, Reinhard Schwesinger, Vladislav M. Vlasov.
Abstract
A UV-vis spectrophotometric method for measurements of relative acidities in heptane has been developed. The phosphazene base t-BuP(4) is used as the deprotonating agent. Its protonated form is a good counterion for the anions of the acids because it is bulky, has delocalized charge, and therefore does not have specific interactions with the anions. A self-consistent scale of relative acidities in heptane spanning for 3 pK(a) units has been constructed.Entities:
Year: 1997 PMID： 11671989 DOI： 10.1021/jo9713013
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354