Literature DB >> 11670346

Synthesis and Structure of the Zintl-Phase K(4)Pb(9) Containing Isolated Pb(9)(4)(-) Clusters of Two Different Geometries.

Virginie Queneau1, Slavi C. Sevov.   

Abstract

The first nine-atom deltahedral clusters of lead in the solid state are found in the Zintl-phase K(4)Pb(9). The compound crystallizes in the monoclinic space group P2(1)/m, Z = 4, with a = 9.648(3) Å, b = 13.243(5) Å, c = 15.909(8) Å, and beta = 103.24(4) degrees. The isolated Pb(9)(4)(-) clusters are of two different geometries, a monocapped square antiprism and an elongated tricapped trigonal prism.

Entities:  

Year:  1998        PMID： 11670346     DOI： 10.1021/ic971225m

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  Chemi-Inspired Silicon Allotropes-Experimentally Accessible Si9 Cages as Proposed Building Block for 1D Polymers, 2D Sheets, Single-Walled Nanotubes, and Nanoparticles.

Authors:  Laura-Alice Jantke; Antti J Karttunen; Thomas F Fässler
Journal:  Molecules       Date:  2022-01-26       Impact factor: 4.411

Review 2.  Current advances in tin cluster chemistry.

Authors:  Bertram Peters; Niels Lichtenberger; Eike Dornsiepen; Stefanie Dehnen
Journal:  Chem Sci       Date:  2019-10-21       Impact factor: 9.825
  2 in total

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