Literature DB >> 11574030

Palladium-catalyzed cross-coupling reactions of in situ generated allylindium reagents with aryl halides.

P H Lee1, S Sung, K Lee.   

Abstract

[reaction: see text] In situ generated allylindium reagents from the reaction of 1 equiv of indium with 1.5 equiv of allyl halides could be effective cross-coupling partners in palladium-catalyzed cross-coupling reactions to aryl halides. The best results were obtained with 2% Pd(2)dba(3)CHCl(3) and 16% Ph(3)P in the presence of 3 equiv of LiCl in DMF at 100 degrees C.

Entities:  

Year:  2001        PMID： 11574030     DOI： 10.1021/ol016532h

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Synthesis of (+)-didemniserinolipid B: application of a 2-allyl-4-fluorophenyl auxiliary for relay ring-closing metathesis.

Authors:  Christopher C Marvin; Eric A Voight; Judy M Suh; Christopher L Paradise; Steven D Burke
Journal:  J Org Chem       Date:  2008-09-24       Impact factor: 4.354

2.  A sequential indium-mediated aldehyde allylation/palladium-catalyzed cross-coupling reaction in the synthesis of 2-deoxy-beta-C-aryl glycosides.

Authors:  John Alec Moral; Seong-Jin Moon; Samuel Rodriguez-Torres; Thomas G Minehan
Journal:  Org Lett       Date:  2009-08-20       Impact factor: 6.005

3.  Palladium-catalyzed reactions of arylindium reagents prepared directly from aryl iodides and indium metal.

Authors:  Vardan Papoian; Thomas Minehan
Journal:  J Org Chem       Date:  2008-08-22       Impact factor: 4.354

4.  MIDA boronate allylation - synthesis of ibuprofen.

Authors:  David Phillips; Glen Brodie; Sarah Memarzadeh; Gi Lum Tang; David J France
Journal:  RSC Adv       Date:  2020-08-18       Impact factor: 3.361
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.