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Literature DB >> 11572696

A simple, mild, catalytic, enantioselective addition of terminal acetylenes to aldehydes.

N K Anand¹, E M Carreira.

Abstract

Entities: Chemical

Mesh：

Substances：
Aldehydes
Acetylene

Year: 2001 PMID： 11572696 DOI： 10.1021/ja016378u

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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41 in total

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Journal: Proc Natl Acad Sci U S A Date: 2004-04-05 Impact factor: 11.205

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3. Density functional computations of enantioselective alkynylation of aldehyde catalyzed by chiral zinc(II)-complexes.

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Journal: J Am Chem Soc Date: 2007-02-06 Impact factor: 15.419

A simple, mild, catalytic, enantioselective addition of terminal acetylenes to aldehydes.

1. Cu(I)-catalyzed direct addition and asymmetric addition of terminal alkynes to imines.

2. Dinuclear Zn-catalyzed asymmetric alkynylation of unsaturated aldehydes.

3. Density functional computations of enantioselective alkynylation of aldehyde catalyzed by chiral zinc(II)-complexes.

4. A green chemistry approach to asymmetric catalysis: solvent-free and highly concentrated reactions.

5. Total syntheses, fragmentation studies, and antitumor/antiproliferative activities of FR901464 and its low picomolar analogue.

6. Total synthesis of the Hsp90 inhibitor geldanamycin.

7. Enantioselective copper-catalyzed alkynylation of benzopyranyl oxocarbenium ions.

8. Development of Zn-ProPhenol-catalyzed asymmetric alkyne addition: synthesis of chiral propargylic alcohols.

9. Total synthesis and stereochemical assignment of (-)-ushikulide A.

10. Mitomycins syntheses: a recent update.