Literature DB >> 11541726

Detection of interstellar ethylene oxide (c-C2H4O).

J E Dickens1, W M Irvine, M Ohishi, M Ikeda, S Ishikawa, A Nummelin, A Hjalmarson.   

Abstract

We report the identification of 10 transitions that support the detection of the small cyclic molecule ethylene oxide (c-C2H4O) in Sgr B2N. Although one of these transitions is severely blended, so that an accurate intensity and line width could not be determined, and two other lines are only marginally detected, we have done Gaussian fits to the remaining seven lines and have performed a rotation diagram analysis. Our results indicate a rotation temperature T(rot) = 18 K and a molecular column density N(c-C2H4O) = 3.3 x 10(14) cm-2, corresponding to a fractional abundance relative to molecular hydrogen of order 6 x 10(-11). This is a factor of more than 200 higher than the abundance for this molecule suggested by the "new standard" chemistry model of Lee, Bettens, & Herbst. This result suggests that grain chemistry might play an effective role in the production of c-C2H4O. No transitions of this molecule were detected in either Sgr B2M or Sgr B2NW.

Entities:  

Keywords:  NASA Discipline Exobiology; Non-NASA Center

Mesh:

Substances:

Year:  1997        PMID: 11541726     DOI: 10.1086/304821

Source DB:  PubMed          Journal:  Astrophys J        ISSN: 0004-637X            Impact factor:   5.874


  6 in total

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Journal:  Proc Natl Acad Sci U S A       Date:  2016-05-31       Impact factor: 11.205

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Authors:  Reggie L Hudson; Falvia M Coleman
Journal:  ACS Earth Space Chem       Date:  2019-05-17       Impact factor: 3.475

3.  Testing Densities and Refractive Indices of Extraterrestrial Ice Components Using Molecular Structures - Organic Compounds and Molar Refractions.

Authors:  Reggie L Hudson; Mark J Loeffler; Robert F Ferrante; Perry A Gerakines; Falvia M Coleman
Journal:  Astrophys J       Date:  2020-02-28       Impact factor: 5.874

4.  Dust evolution, a global view: III. Core/mantle grains, organic nano-globules, comets and surface chemistry.

Authors:  A P Jones
Journal:  R Soc Open Sci       Date:  2016-12-14       Impact factor: 2.963

5.  Isomerization and Fragmentation Reactions on the [C2SH4] Potential Energy Surface: The Metastable Thione S-Methylide Isomer.

Authors:  Zoi Salta; Marc E Segovia; Aline Katz; Nicola Tasinato; Vincenzo Barone; Oscar N Ventura
Journal:  J Org Chem       Date:  2021-01-27       Impact factor: 4.354

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Journal:  Astrophys J       Date:  2014-04-20       Impact factor: 5.874

  6 in total

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