Literature DB >> 11536752

A search for interstellar oxiranecarbonitrile (C3H3NO).

J E Dickens1, W M Irvine, M Ohishi, G Arrhenius, S Pitsch, A Bauder, F Muller, A Eschenmoser.   

Abstract

We report a search in cold, quiescent and in 'hot core' type interstellar molecular clouds for the small cyclic molecule oxiranecarbonitrile (C3H3NO), which has been suggested as a precursor of important prebiotic molecules. We have determined upper limits to the column density and fractional abundance for the observed sources and find that, typically, the fractional abundance by number relative to molecular hydrogen of C3H3NO is less than a few times 10(-10). This limit is one to two orders of magnitude less than the measured abundance of such similarly complex species as CH3CH2CN and HCOOCH3 in well-studied hot cores. A number of astrochemical discoveries were made, including the first detection of the species CH3CH2CN in the massive star-forming clouds G34.3+0.2 and W51M and the first astronomical detections of some eight rotational transitions of CH3CH2CN, CH3CCH, and HCOOCH3. In addition, we found 8 emission lines in the 89 GHz region and 18 in the 102 GHz region which we were unable to assign.

Entities:  

Keywords:  NASA Discipline Exobiology; Non-NASA Center

Mesh:

Substances:

Year:  1996        PMID: 11536752     DOI: 10.1007/bf01809850

Source DB:  PubMed          Journal:  Orig Life Evol Biosph        ISSN: 0169-6149            Impact factor:   1.950


  7 in total

Review 1.  Earth's early atmosphere.

Authors:  J F Kasting
Journal:  Science       Date:  1993-02-12       Impact factor: 47.728

2.  Measurements of the H2(13)CO ortho/para ratio in cold dark molecular clouds.

Authors:  Y C Minh; J E Dickens; W M Irvine; D McGonagle
Journal:  Astron Astrophys       Date:  1995-06-01       Impact factor: 5.802

3.  Spectral scan of Orion A and IRC+10216 from 72 to 91 GHz.

Authors:  L E Johansson; C Andersson; J Ellder; P Friberg; A Hjalmarson; B Hoglund; W M Irvine; H Olofsson; G Rydbeck
Journal:  Astron Astrophys       Date:  1984       Impact factor: 5.802

4.  Organic compound synthesis on the primitive earth.

Authors:  S L MILLER; H C UREY
Journal:  Science       Date:  1959-07-31       Impact factor: 47.728

5.  Mineral induced formation of sugar phosphates.

Authors:  S Pitsch; A Eschenmoser; B Gedulin; S Hui; G Arrhenius
Journal:  Orig Life Evol Biosph       Date:  1995-08       Impact factor: 1.950

6.  Organic molecules in the gas phase of dense interstellar clouds.

Authors:  W M Irvine
Journal:  Adv Space Res       Date:  1995-03       Impact factor: 2.152

Review 7.  Endogenous production, exogenous delivery and impact-shock synthesis of organic molecules: an inventory for the origins of life.

Authors:  C Chyba; C Sagan
Journal:  Nature       Date:  1992-01-09       Impact factor: 49.962

  7 in total
  2 in total

1.  Mineral induced formation of pentose-2,4-bisphosphates.

Authors:  R Krishnamurthy; S Pitsch; G Arrhenius
Journal:  Orig Life Evol Biosph       Date:  1999-03       Impact factor: 1.950

2.  Formation of glycolaldehyde phosphate from glycolaldehyde in aqueous solution.

Authors:  R Krishnamurthy; G Arrhenius; A Eschenmoser
Journal:  Orig Life Evol Biosph       Date:  1999-08       Impact factor: 1.950

  2 in total

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