Literature DB >> 11513573

The gas-phase chemistry of cyclodextrin inclusion complexes.

C B Lebrilla1.   

Abstract

Complexes of cyclodextrins with amino acid analytes are produced in the gas phase and are ideal for the study of molecular recognition. In this Account, we discuss the evidence for the presence of gas-phase inclusion complexes and the nature of the interaction. The use of cyclodextrins as chiral selectors in gas-phase guest-exchange reactions is illustrated, and the nature of the enantioselectivity is discussed. The development of the enantioselective reaction into an analytical method for determining enantiomeric excess is also described.

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Year:  2001        PMID： 11513573     DOI： 10.1021/ar980125x

Source DB:  PubMed          Journal:  Acc Chem Res        ISSN： 0001-4842            Impact factor:   22.384


  14 in total

1.  ESI-MS of Cucurbituril Complexes Under Negative Polarity.

Authors:  Maria A A Rodrigues; Débora C Mendes; Vaidhyanathan Ramamurthy; José P Da Silva
Journal:  J Am Soc Mass Spectrom       Date:  2017-07-29       Impact factor: 3.109

2.  Influence of Single Skimmer Versus Dual Funnel Transfer on the Appearance of ESI-Generated LiCl Cluster/ß-Cyclodextrin Inclusion Complexes.

Authors:  Ina D Kellner; Thomas Drewello
Journal:  J Am Soc Mass Spectrom       Date:  2015-04-21       Impact factor: 3.109

3.  Gas-Phase Fragmentation of Host-Guest Complexes of Cyclodextrins and Polyoxometalates.

Authors:  Pei Su; Andrew J Smith; Jonas Warneke; Julia Laskin
Journal:  J Am Soc Mass Spectrom       Date:  2019-08-14       Impact factor: 3.109

4.  Inclusion complexes of ionic liquids and cyclodextrins: are they formed in the gas phase?

Authors:  Ana M Fernandes; Bernd Schröder; Tânia Barata; Mara G Freire; João A P Coutinho
Journal:  J Am Soc Mass Spectrom       Date:  2014-03-01       Impact factor: 3.109

5.  Distinctive unimolecular gas-phase reactivity of [M(en)2]2+ (M = Ni, Cu) dications and their inclusion complexes with the macrocyclic cavitand cucurbit[8]uril.

Authors:  Tatyana Mitkina; Vladimir Fedin; Rosa Llusar; Ivan Sorribes; Cristian Vicent
Journal:  J Am Soc Mass Spectrom       Date:  2007-07-29       Impact factor: 3.109

6.  Host-guest hydrogen atom transfer induced by electron capture.

Authors:  Changtong Hao; Frantisek Turecek
Journal:  J Am Soc Mass Spectrom       Date:  2008-12-09       Impact factor: 3.109

7.  Dication induced stabilization of gas-phase ternary beta-cyclodextrin inclusion complexes observed by electrospray mass spectrometry.

Authors:  Yang Cai; Matthew A Tarr; Guoxiang Xu; Talat Yalcin; Richard B Cole
Journal:  J Am Soc Mass Spectrom       Date:  2003-05       Impact factor: 3.109

8.  Using non-covalent complexes to direct the fragmentation of glycosidic bonds in the gas phase.

Authors:  Ana K Vrkic; Richard A J O'Hair
Journal:  J Am Soc Mass Spectrom       Date:  2004-05       Impact factor: 3.109

9.  Supramolecular Adducts of Cucurbit[7]uril and Amino Acids in the Gas Phase.

Authors:  Ekaterina Kovalenko; Marta Vilaseca; Mireia Díaz-Lobo; A N Masliy; Cristian Vicent; Vladimir P Fedin
Journal:  J Am Soc Mass Spectrom       Date:  2015-10-06       Impact factor: 3.109

10.  On the specificity of cyclodextrin complexes detected by electrospray mass spectrometry.

Authors:  Valérie Gabelica; Nives Galic; Edwin De Pauw
Journal:  J Am Soc Mass Spectrom       Date:  2002-08       Impact factor: 3.109
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