| Literature DB >> 11506625 |
Y Sakamoto1, G Matsuo, H Matsukura, T Nakata.
Abstract
[structure: see text]. The stereoselective syntheses of the C'D'E'F'-ring system of maitotoxin and the FG-ring system of gambierol were accomplished. The key steps involve 6-endo-cyclization of methylepoxide, SmI2-induced reductive cyclization, 6-endo-cyclization of vinylepoxide, and formation of the lactone ring.Entities:
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Year: 2001 PMID： 11506625 DOI： 10.1021/ol016355k
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005