Literature DB >> 11506624

Titanium-mediated alkylative cyclizations of 1,3-diene-tethered esters.

L G Quan1, J K Cha.   

Abstract

[reaction: see text]. An alkylative titanium-mediated cyclization reaction of 1,3-diene-tethered carboxylic esters has been developed by employing an in situ generated titanacyclopropane intermediate to afford trans-2-alkenyl cyclohexanols.

Entities:  

Year:  2001        PMID： 11506624     DOI： 10.1021/ol016350n

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Direct, redox-neutral prenylation and geranylation of secondary carbinol C-H bonds: C4-regioselectivity in ruthenium-catalyzed C-C couplings of dienes to α-hydroxy esters.

Authors:  Joyce C Leung; Laina M Geary; Te-Yu Chen; Jason R Zbieg; Michael J Krische
Journal:  J Am Chem Soc       Date:  2012-09-17       Impact factor: 15.419

2.  Olefin Exchange-Mediated Cyclopropanation of Nitriles with Homoallylic Alcohols.

Authors:  Denis N Bobrov; Keunho Kim; Jin Kun Cha
Journal:  Tetrahedron Lett       Date:  2008-06-23       Impact factor: 2.415
  2 in total

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