Literature DB >> 11506615

Radical [3+2] annulation of N-allyl-N-chlorotosylamide with alkenes via atom-transfer process.

T Tsuritani1, H Shinokubo, K Oshima.   

Abstract

[reaction: see text]. A radical [3+2] annulation reaction with an N-centered radical has been developed. The reaction of alkenes with N-allyl-N-chlorotosylamide yields the corresponding pyrrolidine derivatives in good yields in the presence of Et3B as a radical initiator.

Entities:  

Year:  2001        PMID： 11506615     DOI： 10.1021/ol016310j

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Enantioselective direct α-amination of aldehydes via a photoredox mechanism: a strategy for asymmetric amine fragment coupling.

Authors:  Giuseppe Cecere; Christian M König; Jennifer L Alleva; David W C MacMillan
Journal:  J Am Chem Soc       Date:  2013-07-26       Impact factor: 15.419

2.  Pyrrolidine and piperidine formation via copper(II) carboxylate-promoted intramolecular carboamination of unactivated olefins: diastereoselectivity and mechanism.

Authors:  Eric S Sherman; Peter H Fuller; Dhanalakshmi Kasi; Sherry R Chemler
Journal:  J Org Chem       Date:  2007-04-12       Impact factor: 4.354

3.  Intermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compounds.

Authors:  Gerold Heuger; Richard Göttlich
Journal:  Beilstein J Org Chem       Date:  2015-07-21       Impact factor: 2.883

4.  Bifunctional sulfilimines enable synthesis of multiple N-heterocycles from alkenes.

Authors:  Qiang Cheng; Zibo Bai; Srija Tewari; Tobias Ritter
Journal:  Nat Chem       Date:  2022-07-25       Impact factor: 24.274
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.