Literature DB >> 11506614

B(C6F5)3-catalyzed allylation of secondary benzyl acetates with allylsilanes.

M Rubin1, V Gevorgyan.   

Abstract

[reaction: see text]. A highly effective protocol for allylation of secondary benzylic alcohol derivatives with allylsilanes in the presence of catalytic amounts of B(C6F5)3 has been developed. Some additional functionalities, such as bromo, acetoxy, and primary benzyloxy groups, were tolerated under these conditions.

Entities:  

Year:  2001        PMID: 11506614     DOI: 10.1021/ol016300i

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  6 in total

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