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Literature DB >> 11483044

Direct asymmetric aldol reactions of acetone using bimetallic zinc catalysts.

Abstract

[reaction: see text] The enantioselective aldol reaction using a novel binuclear zinc catalyst of acetone with several aldehydes gave products in good yields (62-89%) with a high level of enantioselectivity (ee = 76-92%).

Entities: Chemical

Mesh：

Substances：
Acetone
Zinc

Year: 2001 PMID： 11483044 DOI： 10.1021/ol0161211

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

Keyword Cloud
Cited

11 in total

Review 1. The direct catalytic asymmetric aldol reaction.

Authors: Barry M Trost; Cheyenne S Brindle
Journal: Chem Soc Rev Date: 2010-02-17 Impact factor: 54.564

2. Dinuclear Zn-catalyzed asymmetric alkynylation of unsaturated aldehydes.

Authors: Barry M Trost; Andrew H Weiss; Axel Jacobi von Wangelin
Journal: J Am Chem Soc Date: 2006-01-11 Impact factor: 15.419

3. Direct asymmetric Zn-aldol reaction of methyl vinyl ketone and its synthetic applications.

Authors: Barry M Trost; Seunghoon Shin; Joseph A Sclafani
Journal: J Am Chem Soc Date: 2005-06-22 Impact factor: 15.419

4. Enantioselective ProPhenol-catalyzed addition of 1,3-diynes to aldehydes to generate synthetically versatile building blocks and diyne natural products.

Authors: Barry M Trost; Vincent S Chan; Daisuke Yamamoto
Journal: J Am Chem Soc Date: 2010-04-14 Impact factor: 15.419

Direct asymmetric aldol reactions of acetone using bimetallic zinc catalysts.

Review 1. The direct catalytic asymmetric aldol reaction.

2. Dinuclear Zn-catalyzed asymmetric alkynylation of unsaturated aldehydes.

3. Direct asymmetric Zn-aldol reaction of methyl vinyl ketone and its synthetic applications.

4. Enantioselective ProPhenol-catalyzed addition of 1,3-diynes to aldehydes to generate synthetically versatile building blocks and diyne natural products.

5. Total synthesis and stereochemical assignment of (-)-ushikulide A.

6. Exploiting orthogonally reactive functionality: synthesis and stereochemical assignment of (-)-ushikulide A.

7. Broad Spectrum Enolate Equivalent for Catalytic Chemo-, Diastereo-, and Enantioselective Addition to N-Boc Imines.

8. Catalytic Asymmetric Mannich Reactions with Fluorinated Aromatic Ketones: Efficient Access to Chiral β-Fluoroamines.

9. Development of ProPhenol ligands for the diastereo- and enantioselective synthesis of β-hydroxy-α-amino esters.

10. ProPhenol-catalyzed asymmetric additions by spontaneously assembled dinuclear main group metal complexes.