| Literature DB >> 11466044 |
Abstract
A simple spectrophotometric method for the evaluation of formation constants for aqueous copper(I) has been developed, based on the kinetics of reduction of Co(III)(NH(3))(5)X complexes. The method has been applied to the aqueous copper(I)-acetonitrile system to determine the successive formation constants beta(1), beta(2), and beta(3) as 4.3 x 10(2) M(-)(1), 1.0 x 10(4) M(-)(2), and 2.0 x 10(4) M(-)(3), respectively, in 0.14 M NaClO(4)/HClO(4) at 21 +/- 1 degrees C.Entities:
Year: 2001 PMID: 11466044 DOI: 10.1021/ic001447b
Source DB: PubMed Journal: Inorg Chem ISSN: 0020-1669 Impact factor: 5.165