Literature DB >> 11463320

LiCB(11)Me(12): a catalyst for pericyclic rearrangements.

S Moss1, B T King, A de Meijere, S I Kozhushkov, P E Eaton, J Michl.   

Abstract

[structure: see text] Benzene and 1,2-dichloroethane solutions of the Li(+) salt of the weakly coordinating anion CB(11)Me(12)(-) catalyze the rearrangement of cubane to cuneane, quadricyclane to norbornadiene, basketene to Nenitzescu's hydrocarbon, and diademane to triquinacene. The Claisen rearrangement of phenyl allyl ether is also strongly accelerated.

Entities:  

Year:  2001        PMID: 11463320     DOI: 10.1021/ol0161864

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.

Authors:  Christopher A Reed
Journal:  Acc Chem Res       Date:  2010-01-19       Impact factor: 22.384

2.  Gas-phase lithium cation basicity: revisiting the high basicity range by experiment and theory.

Authors:  Charly Mayeux; Peeter Burk; Jean-Francois Gal; Ivari Kaljurand; Ilmar Koppel; Ivo Leito; Lauri Sikk
Journal:  J Am Soc Mass Spectrom       Date:  2014-09-05       Impact factor: 3.109

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.