Metabolic modelling of full-scale biological nitrogen and phosphorus removing wwtp's.

This paper evaluates the experiences with modelling full-scale biological phosphorus and nitrogen removing wastewater treatment plants. For the simulation, we used a metabolic phosphorus model integrated in ASM2d, further referred to as TUDP-model. It was found that the metabolic model for bio-P removal can be applied for modelling full-scale wwtp's, without extensive parameter adjustments. A stepwise modelling approach was proposed. Only three specific parameters were calibrated. Two parameters, the inert fraction in the influent and the actual anoxic sludge fraction will need calibration for all systems. Parameter sensitivity analyses showed that the sensitivity of operational data, often considered as known input data, is high. The model kinetics were found less sensitive. This will in general be the case for all low-loaded wwtp's recorded in their pseudo-steady state. Based on mass balance calculations, operational data and measurements were evaluated. Since all terms on a phosphorus balance can be measured, errors in operational data (e.g. SRT and flow rates) become very apparent in P-removal models (ASM2d, TUDP). We suggest using the P-balance in general for wwtp modelling, as a check on data consistency. This study showed that considering operational data per definition as known input data is not justified. Therefore, operational data should be evaluated, or considered in model calibration over the use of kinetic and stoichiometric parameters.