| Literature DB >> 11429860 |
M V Reddy1, J P Rearick, N Hoch, P V Ramachandran.
Abstract
[figure: see text] This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of alpha,beta-acetylenic alcohols is also described.Entities:
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Year: 2001 PMID： 11429860 DOI： 10.1021/ol006583z
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005