| Literature DB >> 11429857 |
F Gallou1, D W MacMillan, L E Overman, L A Paquette, L D Pennington, J Yang.
Abstract
[figure: see text] Two distinctively different total syntheses of natural sclerophytin A in its revised structural formulation are reported. The first proceeds from (S)-carvone via a cladiellene triol and involves photoisomerization of the double bond. The second route makes use of (5S)-5-(d-menthyloxy)-2(5H)-furanone, which is subjected to cycloaddition, Claisen ring expansion, and regiocontrolled dihydroxylation tactics.Entities:
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Year: 2001 PMID： 11429857 DOI： 10.1021/ol000345m
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005