| Literature DB >> 11421787 |
Abstract
Treatment of perfluoroalkyl chlorides (R(F)Cl) with alkenes, alkynes, or aromatics in the presence of 0.1 equiv of nickel dichloride, 1.5 equiv of zinc powder, and 0.4 equiv of triphenylphosphine in DMF at 95-100 degrees C for 6-8 h give the corresponding perfluoroalkylated products in good yields. A single electron-transfer mechanism is suggested.Entities:
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Year: 2001 PMID： 11421787 DOI： 10.1021/jo010178j
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354