Literature DB >> 11408674

A molybdenum complex with 4,7-diphenyl-1,10-phenanthroline.

X J Xie1, X L Jin, K L Tang.   

Abstract

In the title compound, tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum(0), [Mo(C24H16N2)(CO)4], the Mo-atom coordination is distorted octahedral, with two CO groups cis to each other, but each trans to an N atom of the 4,7-diphenyl-1,10-phenanthroline (dpphen) ligand, and with the other two CO groups trans to each other and on the axis position. The complex has better solubility than [Mo(phen)(CO)4], where phen is 1,10-phenanthroline.

Entities:  

Year:  2001        PMID: 11408674     DOI: 10.1107/s0108270101004164

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Microwave assisted synthesis of molybdenum and tungsten tetracarbonyl complexes with a pyrazolylpyridine ligand. Crystal structure of cis-[Mo(CO)4{ethyl[3-(2-pyridyl)-1-pyrazolyl]acetate}].

Authors:  Ana C Coelho; Filipe A Almeida Paz; Jacek Klinowski; Martyn Pillinger; Isabel S Gonçalves
Journal:  Molecules       Date:  2006-12-06       Impact factor: 4.411

  1 in total

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