| Literature DB >> 11405681 |
Abstract
The installation of the novel N,N-dimethylglycolamide ester auxiliary onto the C(1)-position of protected neuraminic acid donors allows for the exploitation of C(1)-neighboring group participation to generate sialoside conjugates with good to excellent alpha-selectivity under a variety of sialylation protocols, including those that would otherwise lead to nonselective or beta-selective sialoside products.Entities:
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Year: 2001 PMID： 11405681 DOI： 10.1021/ol015854i
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005