| Literature DB >> 11389617 |
F Robert1, A Milet, Y Gimbert, D Konya, A E Greene.
Abstract
Alkyne-dicobalt hexacarbonyl complexes have been studied by DFT to examine whether electronic differences in the acetylenic substituents could play a role in determining the regiochemical outcome in the Pauson-Khand reaction. It appears that in some instances the regiochemistry is, in fact, governed exclusively by the electronic nature of the acetylenic substituents through the discriminant loss of a carbon monoxide ligand.Entities:
Year: 2001 PMID： 11389617 DOI： 10.1021/ja004170n
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419