Literature DB >> 11388857

Basicity of some organic superbases in acetonitrile.

B Kovacevic1, Z B Maksic.   

Abstract

[structure: see text] It is shown that the pK(a) values of strong neutral organic (super)bases in acetonitrile are well described by the density functional theory (DFT) employing the isodensity polarization continuum model (IPCM) for treating solvent-solute interactions. High pK(a) values are predicted for two model compounds, and their synthesis is strongly recommended.

Entities:  

Year:  2001        PMID： 11388857     DOI： 10.1021/ol0158415

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  2-Benzoyl-1-(2,4-dichloro-phen-yl)-3-phenyl-guanidine.

Authors:  Ghulam Murtaza; Masahiro Ebihara; Muhammad Said; M Khawar Rauf; Saeed Anwar
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-08-29

2.  (Z)-2-Phenyl-3-pivaloyl-1,1-dipropyl-guanidine.

Authors:  Muhammad Said; Ghulam Murtaza; Eva Freisinger; Saeed Anwar; Abdur Rauf
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-08-08

3.  Aerobic Oxidation of Benzylic Carbons Using a Guanidine Base.

Authors:  Seulchan Lee; Si Ae Kim; Hye-Young Jang
Journal:  ACS Omega       Date:  2019-10-15

4.  Aluminium alkyl complexes supported by imino-phosphanamide ligand as precursors for catalytic guanylation reactions of carbodiimides.

Authors:  Himadri Karmakar; Srinivas Anga; Tarun K Panda; Vadapalli Chandrasekhar
Journal:  RSC Adv       Date:  2022-02-03       Impact factor: 3.361

5.  Amino-[(1H-benzimidazol-2-yl)amino]-methaniminium 4-methyl-benzene-sulfonate.

Authors:  Shaaban K Mohamed; Mehmet Akkurt; Mahmoud A A Elremaily; Ali M Ali; Mustafa R Albayati
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-09-18

6.  Design of non-ionic carbon superbases: second generation carbodiphosphoranes.

Authors:  Sebastian Ullrich; Borislav Kovačević; Björn Koch; Klaus Harms; Jörg Sundermeyer
Journal:  Chem Sci       Date:  2019-08-16       Impact factor: 9.825
  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.