Mössbauer study of atmospheric aerosols of Shanghai.

Three iron-containing atmospheric aerosol samples were collected, one at a tunnel, one near a viaduct, and one at a park in Shanghai City. These samples were studied by Mössbauer spectroscopy. The experimental results show that ultrafine particles alpha-Fe2O3 (about 13 nm) are the main component of the iron-containing atmospheric aerosols in the tunnel, and high-spin Fe3+ in sulfate containing a small amount of alpha-FeOOH is the main component of iron-containing particles in the aerosols from the other two places. The concentrations of iron in these locations, compared with those of some foreign cities, are much higher. To explore the chemical compositions of iron compounds in aerosols, SPM (scanning proton microprobe) has also been used. From these results, a possible chemical process by which the iron oxides converted to iron sulfate in air was discussed.