Polarization rotation via a monoclinic phase in the piezoelectric 92% PbZn(1/3)Nb(2/3)O3-8% PbTiO3.

The origin of ultrahigh piezoelectricity in the relaxor ferroelectric PbZn(1/3)Nb(2/3)O3-PbTiO3 was studied with an electric field applied along the [001] direction. The zero-field rhombohedral R phase starts to follow the direct polarization path to tetragonal symmetry via an intermediate monoclinic M phase, but then jumps irreversibly to an alternate path involving a different type of monoclinic distortion. Details of the structure and domain configuration of this novel phase are described. This result suggests that there is a nearby R-M phase boundary as found in the Pb(Ti,Zr)O3 system.