Literature DB >> 11312958

Aluminum-controlled reactivity and diastereoselectivity toward radical reactions of optically active aldimines with metallic samarium.

R Yanada1, M Okaniwa, A Kaieda, T Ibuka, Y Takemoto.   

Abstract

The intermolecular pinacol-type coupling reaction and allylation reaction of optically active imines bearing a beta-hydroxy group were performed stereoselectively with metallic samarium after treatment of the imines with trimethylaluminum.

Entities:  

Year:  2001        PMID： 11312958     DOI： 10.1021/jo0014616

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  1 in total

1.  Asymmetric synthesis of α-alkenyl homoallylic primary amines via 1,2-addition of Grignard reagent to α,β-unsaturated phosphonyl imines.

Authors:  Yiwen Xiong; Haibo Mei; Chen Xie; Jianlin Han; Guigen Li; Yi Pan
Journal:  RSC Adv       Date:  2013-01-01       Impact factor: 3.361
  1 in total

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