Dynamic phase transitions in confined lubricant fluids under shear.

A surface force apparatus was used to measure the transient and steady-state friction forces between molecularly smooth mica surfaces confining thin films of squalane, C30H62, a saturated, branched hydrocarbon liquid. The dynamic friction "phase diagram" was determined under different shearing conditions, especially the transitions between stick-slip and smooth sliding "states" that exhibited a chaotic stick-slip regime. The apparently very different friction traces exhibited by simple spherical, linear, and branched hydrocarbon films under shear are shown to be due to the much longer relaxation times and characteristic length scales associated with transitions from rest to steady-state sliding, and vice versa, in the case of branched liquids. The physical reasons and tribological implications for the different types of transitions observed with spherical, linear, and branched fluids are discussed.