| Literature DB >> 11287944 |
L S Dubrovinsky1, N A Dubrovinskaia, V Swamy, J Muscat, N M Harrison, R Ahuja, B Holm, B Johansson.
Abstract
A material as hard as diamond or cubic boron nitride has yet to be identified, but here we report the discovery of a cotunnite-structured titanium oxide which represents the hardest oxide known. This is a new polymorph of titanium dioxide, where titanium is nine-coordinated to oxygen in the cotunnite (PbCl2) structure. The phase is synthesized at pressures above 60 gigapascals (GPa) and temperatures above 1,000 K and is one of the least compressible and hardest polycrystalline materials to be described.Entities:
Year: 2001 PMID: 11287944 DOI: 10.1038/35070650
Source DB: PubMed Journal: Nature ISSN: 0028-0836 Impact factor: 49.962