Literature DB >> 11277797

A xanthate transfer radical process for the introduction of the trifluoromethyl group.

F Bertrand1, V Pevere, B Quiclet-Sire, S Z Zard.   

Abstract

[reaction: see text]. S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a radical mechanism to give adducts with a trifluoromethyl group at the least hindered terminus of the olefin.

Entities:  

Year:  2001        PMID： 11277797     DOI： 10.1021/ol0156446

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  One-pot three-component route for the synthesis of S-trifluoromethyl dithiocarbamates using Togni's reagent.

Authors:  Azim Ziyaei Halimehjani; Martin Dračínský; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2017-11-24       Impact factor: 2.883

2.  The dual role of thiourea in the thiotrifluoromethylation of alkenes.

Authors:  Paolo Ricci; Tanatorn Khotavivattana; Lukas Pfeifer; Maurice Médebielle; John Richard Morphy; Véronique Gouverneur
Journal:  Chem Sci       Date:  2016-09-30       Impact factor: 9.825

3.  Synthesis of novel 1-[(2,6-dichloro-4-trifluoromethyl)phenyl]-3-aryl-1H-pyrazole-4-carbaldehydes.

Authors:  Huanan Hu; Changhua Ge; Lisheng Ding; Anjiang Zhang
Journal:  Molecules       Date:  2010-10-25       Impact factor: 4.411

4.  Metal-free alkene oxy- and amino-perfluoroalkylations via carbocation formation by using perfluoro acid anhydrides: unique reactivity between styrenes and perfluoro diacyl peroxides.

Authors:  Elena Valverde; Shintaro Kawamura; Daisuke Sekine; Mikiko Sodeoka
Journal:  Chem Sci       Date:  2018-08-01       Impact factor: 9.825

5.  Regioselective synthesis of 1-(2,6-dichloro-4-trifluoromethylphenyl)- 4-alkyl-1H-[1,2,3]-triazoles.

Authors:  Huanan Hu; Anjiang Zhang; Lisheng Ding; Xinxiang Lei; Lixue Zhang
Journal:  Molecules       Date:  2008-03-03       Impact factor: 4.411
  5 in total

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