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Literature DB >> 11277795

Stereoselective halogenations of alkenes and alkynes in ionic liquids.

C Chiappe¹, D Capraro, V Conte, D Pieraccini.

Abstract

[reaction: see text]. Room-temperature ionic liquids, 1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium bromide, and 1-butyl-3-methylimidazolium chloride, are used as "green" recyclable alternative to chlorinated solvents for the stereoselective halogenation of alkenes and alkynes.

Entities: Chemical

Year: 2001 PMID： 11277795 DOI： 10.1021/ol015631s

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

7 in total

1. Theoretical study on the interactions between methanol and imidazolium-based ionic liquids.

Authors: Xueying Zhu; Hui Sun; Dongju Zhang; Chengbu Liu
Journal: J Mol Model Date: 2010-12-03 Impact factor: 1.810

2. New insight into the formation mechanism of imidazolium-based halide salts.

Authors: Xueying Zhu; Dongju Zhang; Chengbu Liu
Journal: J Mol Model Date: 2010-12-21 Impact factor: 1.810

3. Accessing molecularly complex azaborines: palladium-catalyzed Suzuki-Miyaura cross-couplings of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.

Authors: Gary A Molander; Steven R Wisniewski
Journal: J Org Chem Date: 2014-07-01 Impact factor: 4.354

Stereoselective halogenations of alkenes and alkynes in ionic liquids.

1. Theoretical study on the interactions between methanol and imidazolium-based ionic liquids.

2. New insight into the formation mechanism of imidazolium-based halide salts.

3. Accessing molecularly complex azaborines: palladium-catalyzed Suzuki-Miyaura cross-couplings of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.

4. Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold.

5. Hypervalent Iodine-Mediated Chemoselective Bromination of Terminal Alkynes.

Review 6. Application of ionic liquids in hydrometallurgy.

Review 7. On the chemical stabilities of ionic liquids.