Literature DB >> 11263914

Iodine monochloride/silver trifluoromethanesulfonate (ICI/AgOTf) as a convenient promoter system for O-glycoside synthesis.

T Ercegovic1, A Meijer, G Magnusson, U Ellervik.   

Abstract

The novel promoter system iodine monochloride/silver trifluoromethanesulfonate (ICl/AgOTf) was evaluated with various thioglycoside donors and saccharide acceptors, and O-glycosides were obtained in 46-82% yield. Several practical advantages of the ICl/AgOTf system over known promoter systems were observed, such as convenient handling of the reagents and absence of byproducts related to N-succinimide.

Entities:  

Mesh:

Substances:

Year:  2001        PMID: 11263914     DOI: 10.1021/ol015547c

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Palladium(II)-assisted activation of thioglycosides.

Authors:  Samira Escopy; Yashapal Singh; Alexei V Demchenko
Journal:  Org Biomol Chem       Date:  2021-03-11       Impact factor: 3.876

2.  A versatile glycosylation strategy via Au(iii) catalyzed activation of thioglycoside donors.

Authors:  Amol M Vibhute; Arun Dhaka; Vignesh Athiyarath; Kana M Sureshan
Journal:  Chem Sci       Date:  2016-03-08       Impact factor: 9.825

3.  1,3-Dibromo-5,5-dimethylhydantoin as promoter for glycosylations using thioglycosides.

Authors:  Fei-Fei Xu; Claney L Pereira; Peter H Seeberger
Journal:  Beilstein J Org Chem       Date:  2017-09-22       Impact factor: 2.883

  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.