| Literature DB >> 11263898 |
D H Live1, Z G Wang, U Iserloh, S J Danishefsky.
Abstract
Glycoproteins contain carbohydrate and peptide sectors. As a model for studying whether there exists stereochemical "communication" between the two domains, we prepared two glycopeptides differing only in the absolute stereochemistry of the peptide domain (L-peptide vs D-peptide). High-field NMR spectroscopy revealed that there are distinct and measurable differences, indicating that the two domains are at some level interactive.Entities:
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Year: 2001 PMID： 11263898 DOI： 10.1021/ol0070233
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005