Literature DB >> 11262129

Palladium-catalyzed allylic alkylation using chiral hydrazones as ligands.

T Mino1, M Shiotsuki, N Yamamoto, T Suenaga, M Sakamoto, T Fujita, M Yamashita.   

Abstract

Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate (4) with a dimethyl malonate-BSA-LiOAc system and its derivatives has been successfully carried out in the presence of a new chiral hydrazone ligands such as 2-(diphenylphosphino)benzaldehyde SAMP hydrazone (DPPBA-SAMP) (3a) in high yields with high enantioselectives.

Entities:  

Year:  2001        PMID: 11262129     DOI: 10.1021/jo0057001

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  N,N-Bis(2-hydroxy-benzyl-idene)-2,2'-bipyridyl-3,3'-dicarbohydrazide.

Authors:  Shao-Bin Miao; Lu-Lu Zang; Ya-Wei Fan; Bao-Ming Ji
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-12-10
  1 in total

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