Literature DB >> 11259062

C-H and C-C bond activation of primary amines through dehydrogenation and transimination.

C H Jun1, K Y Chung, J B Hong.   

Abstract

[structure: see text]. Dehydrogenation and subsequent transimination of primary amines offer a new pathway for C-H bond activation, ortho-alkylation, and C-C bond activation to afford a variety of ketones in the reaction of 1-alkene by a cocatalyt system of Rh(I) and 2-amino-3-picoline.

Entities:  

Year:  2001        PMID: 11259062     DOI: 10.1021/ol015563+

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Efficient Dehydrogenation of Amines and Carbonyl Compounds Catalyzed by a Tetranuclear Ruthenium-mu-Oxo-mu-Hydroxo-Hydride Complex.

Authors:  Chae S Yi; Do W Lee
Journal:  Organometallics       Date:  2009-01-29       Impact factor: 3.876

Review 2.  Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

Authors:  Denise A Colby; Robert G Bergman; Jonathan A Ellman
Journal:  Chem Rev       Date:  2010-02-10       Impact factor: 60.622

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.