| Literature DB >> 11237024 |
A Gáplovský1, J Donovalová, S Toma, R Kubinec.
Abstract
Ultrasound considerably enhances and simplifies photochemical reaction of cyclohexanone with cyclohexene. The Paterno-Büchi reaction of acetone with ethyl vinyl ether is enhanced by ultrasound and yields a different ratio of cis/trans oxetanes under sonication by comparison with the silent reaction. Sonication appears to affect the first reaction by homogenization of excited intermediates and by quenching the excited triplet state at the second reaction.Entities:
Year: 1997 PMID: 11237024 DOI: 10.1016/s1350-4177(97)00004-7
Source DB: PubMed Journal: Ultrason Sonochem ISSN: 1350-4177 Impact factor: 7.491