| Literature DB >> 11101455 |
Abstract
[reaction: see text] An enantiospecific synthesis of a coccinellied alkaloid, (-)-adalinine, was established starting from (S)-(-)-pyroglutamic acid, where a stereoselective Michael addition and a samarium iodide-promoted regioselective carbon-nitrogen bond cleavage reaction were involved as the key reactions.Entities:
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Year: 2000 PMID： 11101455 DOI： 10.1021/ol006712b
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005