Literature DB >> 11101445

Intramolecular hydrogen-bond participation in phosphonylammonium salt formation.

A B Smith1, L Ducry, R M Corbett, R Hirschmann.   

Abstract

[reaction: see text] A series of phosphonochloridates and phosphonyl dichlorides were prepared, and their reactivity with triethylamine has been investigated using (31)P NMR spectroscopy. Taken together these studies provide evidence that an intramolecular hydrogen-bond is required for phosphonylammonium salt formation to render the phosphorus more electron-deficient.

Entities:  

Mesh:

Substances:

Year:  2000        PMID: 11101445     DOI: 10.1021/ol0066330

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Practical Synthesis of Phosphinic Dipeptides by Tandem Esterification of Aminophosphinic and Acrylic Acids under Silylating Conditions.

Authors:  Paraskevi Kokkala; Kostas Voreakos; Angelos Lelis; Konstantinos Patiniotis; Nikolaos Skoulikas; Laurent Devel; Angeliki Ziotopoulou; Eleni Kaloumenou; Dimitris Georgiadis
Journal:  Molecules       Date:  2022-02-12       Impact factor: 4.411

2.  Friedel-Crafts-type reaction of pyrene with diethyl 1-(isothiocyanato)alkylphosphonates. Efficient synthesis of highly fluorescent diethyl 1-(pyrene-1-carboxamido)alkylphosphonates and 1-(pyrene-1-carboxamido)methylphosphonic acid.

Authors:  Anna Wrona-Piotrowicz; Janusz Zakrzewski; Anna Gajda; Tadeusz Gajda; Anna Makal; Arnaud Brosseau; Rémi Métivier
Journal:  Beilstein J Org Chem       Date:  2015-12-04       Impact factor: 2.883

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.