Literature DB >> 11101442

Palladium-catalyzed additions of silyl-element bonds to bicyclopropylidene-A new access to bicyclopropyl and functionally substituted cyclopropylidenepropane derivatives

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Abstract

Palladium-catalyzed additions of disilanes, silylboranes, silylstannanes, and silyl cyanides across the double bond of bicyclopropylidene proceed with remarkable ease by two modes yielding either bicyclopropyl or cyclopropylidenepropane derivatives.

Entities:  

Year:  2000        PMID: 11101442     DOI: 10.1021/ol006618v

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Copper catalyzed borocarbonylation of benzylidenecyclopropanes through selective proximal C-C bond cleavage: synthesis of γ-boryl-γ,δ-unsaturated carbonyl compounds.

Authors:  Li-Miao Yang; Hui-Hui Zeng; Xin-Lian Liu; Ai-Jun Ma; Jin-Bao Peng
Journal:  Chem Sci       Date:  2022-05-30       Impact factor: 9.969

2.  Palladium-catalyzed hydroalkylation of methylenecyclopropanes with simple hydrazones.

Authors:  Jinzhong Yao; Zhangpei Chen; Lin Yu; Leiyang Lv; Dawei Cao; Chao-Jun Li
Journal:  Chem Sci       Date:  2020-05-15       Impact factor: 9.825

  2 in total

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