| Literature DB >> 11093700 |
A W Heinen1, J A Peters, H van Bekkum.
Abstract
The hydrogenation of D-fructose on Ru/C catalysts was studied. Under the conditions applied (1 bar H2, 72 degrees C), the furanose forms of D-fructose react, while the pyranose forms do not. However, all anomers adsorb with comparable strength on the surface. The reaction rate is controlled by product inhibition. The selectivity to D-mannitol can be increased from 47 to 63% by promotion of Pd/C and Pt/C catalysts with Sn.Entities:
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Year: 2000 PMID: 11093700 DOI: 10.1016/s0008-6215(00)00146-4
Source DB: PubMed Journal: Carbohydr Res ISSN: 0008-6215 Impact factor: 2.104