Deuteron NMR study of molecular dynamics in a compound exhibiting a reentrant nematic phase

A deuteron NMR study of molecular dynamics in the partial bilayer smectic A(d) and reentrant nematic phases of a pure chain-deuterated compound is presented. The deuteron spin-lattice relaxation times T(1Z) and T(1Q) were measured as a function of temperature for two different frequencies (15 and 46 MHz). The experimental results were interpreted in terms of the internal conformational motions of a chain decoupled from the molecular small-step rotational diffusion and the order director fluctuations. The latter motion was found to be essential to the fit of experimental results in the reentrant nematic phase. The fitting parameters obtained by using a global target fitting method are acceptable when compared with those obtained from other deuteron and proton NMR studies of the same mesophases.