Literature DB >> 11086684

Characterization of new oxovanadium(IV) complexes of saccharides.

P A Williams1, S B Etcheverry, E Baran.   

Abstract

Oxovanadium(IV) complexes of the monosaccharides D- and L-arabinose, D-galactose, D-mannose, D-lyxose, D-xylose and the disaccharide maltose were obtained in aqueous solutions at pH 13. Their sodium salts were precipitated with absolute ethanol and characterized by UV-vis spectroscopy (absorption and reflectance), thermo-analytical (TG and DTA) data, magnetic susceptibility measurements and IR-spectroscopy. All the complexes were found to be mononuclear, possessing the VO2+ moiety. The IR spectra were analyzed and discussed in detail allowing one to determine the characteristics of the metal-to-ligand interactions.

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Year:  2000        PMID: 11086684     DOI: 10.1016/s0008-6215(00)00171-3

Source DB:  PubMed          Journal:  Carbohydr Res        ISSN: 0008-6215            Impact factor:   2.104


  2 in total

1.  Antioxidant effects of the VO(IV) hesperidin complex and its role in cancer chemoprevention.

Authors:  Susana Beatriz Etcheverry; Evelina Gloria Ferrer; Luciana Naso; Josefina Rivadeneira; Victoria Salinas; Patricia Ana María Williams
Journal:  J Biol Inorg Chem       Date:  2007-12-21       Impact factor: 3.358

2.  Synthesis of a new vanadyl(IV) complex with trehalose (TreVO): insulin-mimetic activities in osteoblast-like cells in culture.

Authors:  Daniel A Barrio; Patricia A M Williams; Ana M Cortizo; Susana B Etcheverry
Journal:  J Biol Inorg Chem       Date:  2003-02-13       Impact factor: 3.358

  2 in total

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