The effect of large anthropogenic particulate emissions on atmospheric aerosols, deposition and bioindicators in the eastern Gulf of Finland region.

The effect of the emissions from large oil shale fuelled power plants and a cement factory in Estonia on the elemental concentration of atmospheric aerosols, deposition, elemental composition of mosses and ecological effects on mosses, lichens and pine trees in the eastern Gulf of Finland region has been studied. In addition to chemical analysis, fly ash, moss and aerosol samples were analysed by a scanning electron microscope with an energy dispersive X-ray spectrometer (SEM/EDS). The massive particulate calcium emissions, approximately 60 kton/year (1992), is clearly observed in the aerosols, deposition and mosses. The calcium deposition is largest next to the Russian border downwind from the power plants and in south-eastern part of Finland. This deposition has decreased due to the application of dust removal systems at the particulate emission sources. At the Virolahti EMEP station approximately 140 km north from the emission sources, elevated elemental atmospheric aerosol concentrations are observed for Al, Ca, Fe, K and Si and during episodes many trace elements, such as As, Br, Mo, Ni, Pb and V. The acidification of the soil is negligible because of the high content of basic cations in the deposition. Visible symptoms on pine trees are negligible. However, in moss samples close to the power plants, up to 25% of the leaf surface was covered by particles. Many epiphytic lichen species do not tolerate basic stemflow and on the other hand most species are also very sensitive for the SO2 content in air. Consequently a large lichen desert is found in an area of 2500 km2 in the vicinity of the power plants with only one out of the investigated 12 species growing.