| Literature DB >> 11029212 |
J T Feutrill1, M J Lilly, M A Rizzacasa.
Abstract
The first asymmetric synthesis of (+)-crocacin C (3) is described which served to confirm the absolute configuration of this compound. The key step in the sequence was the stereoselective assembly of the (E,E)-diene amide side chain by a Stille cross-coupling between the stannane 5 and vinyl iodide 6.Entities:
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Year: 2000 PMID： 11029212 DOI： 10.1021/ol0064664
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005