Phase-sensitive evidence for d-wave pairing symmetry in electron-doped cuprate superconductors

We present phase-sensitive evidence that the electron-doped cuprates Nd(1.85)Ce(0.15)CuO(4-y) (NCCO) and Pr(1.85)Ce(0.15)CuO(4-y) (PCCO) have d-wave pairing symmetry. This evidence was obtained by observing the half-flux quantum effect, using a scanning SQUID microscope, in c-axis-oriented films of NCCO or PCCO epitaxially grown on tricrystal [100] SrTiO3 substrates designed to be frustrated for a d(x(2)-y(2)) order parameter. Samples with two other configurations, designed to be unfrustrated for a d-wave superconductor, do not show the half-flux quantum effect.