| Literature DB >> 10970596 |
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Abstract
Motivated by recent neutron, x-ray absorption, and resonant scattering experiments, we revisit the electronic structure of V2O3. We propose a model in which S = 1 V3+ ions are coupled in the vertical V-V pairs forming twofold orbitally degenerate configurations with S = 2. Ferro-orbital ordering of the V-V pairs gives a description which is consistent with all experiments in the antiferromagnetic insulating phase.Entities:
Year: 2000 PMID: 10970596 DOI: 10.1103/PhysRevLett.85.1714
Source DB: PubMed Journal: Phys Rev Lett ISSN: 0031-9007 Impact factor: 9.161